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Synthesis and Conductivity Studies of Tetraarylphosphonium Salts As Potential Electrolytes in Advanced Batteries

Authors
  • Rebecca Boucard

    Albany State University, Albany GA

    Author

  • Paige Reagan

    Albany State University, Albany GA

    Author

  • Ghislain R Mandouma

    Albany State University, USA

    Author

Abstract

The purpose of this study was to synthesize polysubstituted tetraarylphosphonium/tetrakis (pentafluorophenyl) borate salts 3, also known as TAPR/TFAB where R is a substituent, and to measure their conductance/conductivity in low-polarity media such as tetrahydrofuran (THF) and dichloromethane (DCM). Such determination was to provide a rationale to the question of whether these compounds, and other weakly coordinating cations/anions combinations are suitable electrolytes for advanced batteries which are energized in safer, low-polarity organic solvents.

Author Biographies
  1. Rebecca Boucard, Albany State University, Albany GA

    Department of Chemistry and Forensic Sciences

  2. Paige Reagan, Albany State University, Albany GA

    Department of Chemistry and Forensic Sciences

  3. Ghislain R Mandouma, Albany State University, USA

    Department of Natural Sciences

References

Goodenough, GB, Park, KS. J. Am. Chem. Soc. 2013, 135, 1167-1176; DOI: https://doi.org/10.1021/ja3091438

Etacheri, V.; Marom, R.; Elazari, R.; Salitra, G.; Aurbach, D.; Energy Environ. Sci. 2011, 3243-3262; DOI: https://doi.org/10.1039/c1ee01598b

Armand, M.; Tarascon, J.M. Nature, 2008, 451, 652-657; DOI: https://doi.org/10.1038/451652a

Tarascon, J.M. Philos. Trans. R. Soc., A 2010, 368, 3227-3241 DOI: https://doi.org/10.1098/rsta.2010.0112

Gandini, A; Lacerda, T.M. Prog. Polym. Sci. 2015, 48, 1-39; DOI: https://doi.org/10.1016/j.progpolymsci.2014.11.002

Janoschka, T.; Hager, M.D.; Schubert, U.S.; Adv. Mater. 2012, 24, 6397-6409; DOI: https://doi.org/10.1002/adma.201203119

Nishida, H.; Suga, T.; Electrochemical Society Interface 2005, 32-36; DOI: https://doi.org/10.1149/2.F04054IF

Muench, S; Wild, A; Friebe, C; Haupler, B; Janoschka, T; Schubert, U.S.; Chem. Rev. 2016, 116, 9438-9484; DOI: https://doi.org/10.1021/acs.chemrev.6b00070

Brousse, K.; Martin, C.; Brisse, A.L.; Lethien, C.; Simon, P.; Taberna, P.L.; Brousse, T.;Leung, P.K.; Martin, T.; Shah, A.A.; Mohamed, M.R.; Anderson, M.A.; Palma, J.; Journal of Power Sources, 2017, 360, 243-283;

Wei, X.; Pan, W.; Duan, W.; Hollas, A.M.; Yang, Z.; Li, B.; Nie, Z.; Liu, J.; Reed, D.M.;

Wang, W.; Sprenkle, V.L. ACS Energy Letters, 2017, 2(9):2187- DOI: https://doi.org/10.1021/acsenergylett.7b00650

doi:10.1021/acsenergylett.7b00650;

Li, Y; Wang, X; Dong, S; Chen, X; Cui, G; Adv. Energy Mater. 2016, 6, 1600751; DOI: https://doi.org/10.1002/aenm.201600751

Krossing, I.; Raabe, I.; Angew. Chem. Int. Ed. 2004, 76, 6395-6401;

Geiger, W.E.; Barriere, F.; Accounts Chem Res 2010, 43, 1030-1039; DOI: https://doi.org/10.1021/ar1000023

Mpoukouvalas et al., Mpoukouvalas, K.; Turp, D.; Wagner, M.; Mullen, K.; Butt, H. J.; Floudas, G.; J Phys Chem B 2011, 115, 5801-5806. DOI: https://doi.org/10.1021/jp201324m

Moritz, R,; Stangenberg, R.; Baumgarten, M.; Mullen, K.; Eur. J. Org. Chem. 2015, 7, 1456-1463;

Turp, D.; Wagner, M.; Enkelmann, V.; Mullen, K.; Angew. Chem. Int. Ed., 2011, 50, 4962-4965; DOI: https://doi.org/10.1002/anie.201007070

Zhao, D.S.; Moritz, N.; Laurila, P.; Mattila, R.; Lassila, L.V.J.; Strandberg, N.; Muller,

R.; Macromolecules 2014, 47, 4567-4586; DOI: https://doi.org/10.1021/ma500480z

Wehming, K.; Moritz, S.; Schnakenburg, G.; Waldvogel, S.R.; Chem Eur J 2014, 20(39), 12463-12469; DOI: https://doi.org/10.1002/chem.201403442

LeSuer, R. J.; Buttolph, C.; Geiger, W. E., Anal. Chem., 2004, 76, 6395-6401; DOI: https://doi.org/10.1021/ac040087x

W. Schmickler, Interfacial Electrochemistry, Oxford University press, 1996; DOI: https://doi.org/10.1093/oso/9780195089325.001.0001

O. Popovych and R.P.T. Tomkins, Nonaqueous Solution Chemistry, J. Wiley and Sons, New York, 1981

Grills, D. C.; Cook, A. R.; Fujita, E.; George, M. W.; Preses, J. M.; Wishart, J. F.; Appl. Spectrosc. 2010, 64, 563; DOI: https://doi.org/10.1366/000370210791414344

Marcoux, D.; Charette, A. B. J Org Chem 2008, 73, 590-593; DOI: https://doi.org/10.1021/jo702355c

Moritz, R.; Zardalidis, G.; Butt, H. J.; Wagner, M.; Mullen, K.; Floudas, G., Macromolecules 2014, 47, 191-196; DOI: https://doi.org/10.1021/ma402137x

Yonekuta, Y.; Susuki, K.; Oyaizu, K.; Honda, K.; Nishide, H. J. Am. Chem. Soc. 2007, 129, 14128-14129; DOI: https://doi.org/10.1021/ja075553p

Wei, X.; Duan, W.; Huang, J.; Zhang, L.; Li, B.; Reed, D.; Xu, W.; Sprenkle, V.; Wang, W.; ACS Energy Lett. 2016, 1, 705−711; doi: 10.1021/acsenergylett.6b00255. DOI: https://doi.org/10.1021/acsenergylett.6b00255

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2018-02-01
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How to Cite

Boucard, R. ., Reagan, P. ., & Mandouma, G. R. (2018). Synthesis and Conductivity Studies of Tetraarylphosphonium Salts As Potential Electrolytes in Advanced Batteries. International Journal for Innovation Education and Research, 6(2), 116-123. https://doi.org/10.31686/ijier.vol6.iss2.955